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Dental floss has a history that his maybe longer than of the toothbrush but we know for sure that it is in use since the 19th century. It is in the wider use since the invention of synthetic materials like nylon.
Tooth decay is one of the oldest diseases of the human race. People had caries for millions of years and still have it today. With the appearance of sugar cane and other types of sugar prevalence of caries increased and until the modern treatments of caries, both preventive and remedial, lessen the number and seriousness of caries cases.
History of dentistry is long and ... well - painful. But since the people began using natural ingredients to treat illnesses, they used it for teeth problems also. And slowly but surely, we became more adept in treating tooth decay and other oral problems.
Toothpaste is one of the main ingredients in the process of keeping the teeth healthy. In combination with toothbrush it removes dental plaque and food that remains on the teeth after eating. Read more about history of toothpaste.